Human tear film and meibum. I. Very long chain wax esters and (O-acyl)-omega- hydroxy fatty acids of meibum

نویسندگان

  • Igor A. Butovich
  • Jadwiga Wojtowicz
  • Mike Molai
چکیده

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Human tear film and meibum. Very long chain wax esters and (O-acyl)-omega-hydroxy fatty acids of meibum.

Human meibum was targetly analyzed for the presence of intact wax esters (WEs) and related compounds by means of reverse-phase HPLC in combination with ion trap mass spectrometry. The major detected WEs were based on C(18:n) (n = 1-4) unsaturated FAs ranking in the following order of abundance: C(18:1)>C(18:2)>C(18:3)>C(18:4). The major fatty alcohols (FAls) found in WE were of saturated nature...

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A comparison of patient matched meibum and tear lipidomes.

PURPOSE To quantify the molecular lipid composition of patient-matched tear and meibum samples and compare tear and meibum lipid molecular profiles. METHODS Lipids were extracted from tears and meibum by bi-phasic methods using 10:3 tert-butyl methyl ether:methanol, washed with aqueous ammonium acetate, and analyzed by chip-based nanoelectrospray ionization tandem mass spectrometry. Targeted ...

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Meibum Color and Free Fatty Acid Composition in Patients With Meibomian Gland Dysfunction.

PURPOSE We measured the components of meibum in patients with meibomian gland dysfunction (MGD) and control subjects and then examined the relation between meibum composition and clinical parameters. METHODS Thirty-eight patients with MGD (13 men and 25 women; mean age ± SD, 66.9 ± 15.0 years) and 20 control subjects (8 men and 12 women; 64.5 ± 6.7 years) were enrolled. Ocular symptom score, ...

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Shotgun lipidomic analysis of human meibomian gland secretions with electrospray ionization tandem mass spectrometry.

PURPOSE The purpose of this investigation was to determine the major molecular components of the lipids in normal human meibomian gland secretions (meibum). METHODS The meibum samples were studied by direct infusion electrospray ionization (ESI), quadrupole time-of-flight mass spectrometry, and tandem mass spectrometry (MS/MS) analysis, in both positive and negative detection modes. RESULTS...

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Meibum Lipid Composition in Asians with Dry Eye Disease

BACKGROUND Previous lipidomic analyses of the human meibum had largely focused on individuals from non-Asian populations, despite the higher prevalence of dysfunctional tear syndrome (DTS) observed across Asia. Information pertaining to the alterations in lipid profiles in relation to DTS onset and progression is also lacking and warrants comprehensive experimental analysis. METHODOLOGIES/PRI...

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تاریخ انتشار 2009